- transannular interaction
- Макаров: внутрициклическое взаимодействие
Универсальный англо-русский словарь. Академик.ру. 2011.
transannular interaction
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Transannular interaction — A transannular interaction in chemistry is any chemical interaction (favorable or nonfavorable) between different non bonding molecular groups in a large ring or macrocycle. See for an example the molecule atrane. External links # Experimental… … Wikipedia
Atrane — An Atrane is a tricyclic molecule with three five membered rings. It has a transannular dative bond by a nitrogen atom, depicted as A. The name atrane was first proposed by Mikhail Grigorievich Voronkov.Various atranes are named depending on the… … Wikipedia
Prelog strain — In organic chemistry, transannular strain or Prelog strain (named after Vladimir Prelog) is the unfavorable interaction of transannular protons in 7 12 membered cyclic molecules resulting in increased ring strain. External links # Prelog strain… … Wikipedia
Tiffeneau-Demjanov rearrangement — The Tiffeneau Demjanov rearrangement (TDR) the chemical reaction of 1 aminomethyl cycloalkanols with nitrous acid to form an enlarged cycloketone.Ref|Tiffeneau1937After being in existence for over 65 years, the reaction is popular among organic… … Wikipedia
Tiffeneau–Demjanov rearrangement — The Tiffeneau Demjanov rearrangement (TDR) is the chemical reaction of a 1 aminomethyl cycloalkanol with nitrous acid to form an enlarged cycloketone. The Tiffeneau–Demjanov ring expansion, Tiffeneau–Demjanov rearrangement, or TDR, provides an… … Wikipedia
Johnson–Corey–Chaykovsky reaction — The Johnson–Corey–Chaykovsky reaction (sometimes referred to as the Corey–Chaykovsky reaction or CCR) is a chemical reaction used in organic chemistry for the synthesis of epoxides, aziridines, and cyclopropanes. It was discovered in 1961 by A.… … Wikipedia
